Title Page
요약
Abstract
Contents
Chapter 1. Background for Porphyrin and Previous Studies 9
1-1. Introduction of Porphyrins 9
1-2. Classification of Porphyrin Analogues 9
1-3. Synthesis of Porphyrins 10
1-4. Aromaticity 11
1-5. Photophysical Properties 12
1-6. Previous Studies of Naphthiporphyrins 13
Chapter 2. Synthesis and Characterization of Modified Porphyrins 17
2-1. Modification of Porphyrin: Naphthicorrole 17
2-1.1. Background 17
2-1.2. Synthesis 18
2-1.3. Aromaticity 20
2-1.4. UV-Vis Spectrum 21
2-1.5. Application 22
2-1.6. Conclusion 24
2-2. Modification of Porphyrin: o-Vinylarene-embedded Porphyrins 24
2-2.1. Background 24
2-2.2. Synthesis 26
2-2.3. Aromaticity 26
2-2.4. UV-Vis Spectrum 32
2-2.5. Conclusion 33
2-3. Experimental Section 34
2-4. NMR Spectra 45
Chapter 3. Synthesis and Characterization of Tolan-based Ion Receptors 101
3-1. Tolan-based Li⁺/HSO₄⁻ Selective Receptor 101
3-1.1. Background 101
3-1.2. Synthesis 102
3-1.3. Binding Studies 102
3-1.4. Conclusion 107
3-2. Tolan-based Cd₂⁺ Selective Receptor 107
3-2.1. Background 107
3-2.2. Synthesis 108
3-2.3. Binding Studies 109
3-2.4. Conclusion 114
3-3. Experimental Section 115
3-4. NMR Spectra 120
References 142