표제지
목차
ABSTRACT 18
제1장 서론 21
제1절 연구의 배경과 목적 21
제2절 연구의 범위와 방법 24
1. 연구의 범위 24
2. 연구방법 24
제2장 이론적 배경 25
제1절 염모제 25
1. 염색의 정의 25
2. 염료의 정의 25
3. 염모제의 분류 25
제2절 산화 염모제 30
1. 산화 염모제의 정의 30
2. 산화 염모제의 역사 30
3. 산화 염모제의 주요성분 31
4. 산화 염모제의 작용기전 32
제3절 피그멘테이션 기법 35
1. 프리-피그멘테이션 35
2. 애프터-피그멘테이션 35
제3장 연구방법 36
제1절 연구모형 36
1. 연구모형 36
제2절 실험내용 38
1. 시료모발 38
2. 실험도구 39
3. 측정 도구 및 기기 39
제3절 실험방법 40
1. 실험군 분류 40
2. Non-Pigmentation 염색 40
3. Pre-pigmentation 염색 40
4. After-Pigmentation 염색 41
5. 샴푸 41
6. 주사전자현미경 관찰 41
7. 모발의 인장강도 측정 42
8. 색의 측정 42
9. 메틸렌블루(Methylene blue) 염색법을 이용한 분석 44
제4절 통계 방법 45
제4장 연구결과 및 고찰 46
제1절 피그멘테이션 처리 방법에 따른 모발 색상 비교 46
1. 탈색모의 저명도 레드 염색 시 모발 색상 46
2. 탈색모의 중명도 레드 염색 시 모발 색상 51
3. 탈색모의 고명도 레드 염색 시 모발 색상 56
4. 건강모의 저명도 레드 염색 시 모발 색상 61
5. 건강모의 중명도 레드 염색 시 모발 색상 66
6. 건강모의 고명도 레드 염색 시 모발 색상 71
7. 탈색모의 저명도 블루 염색 시 모발 색상 76
8. 탈색모의 중명도 블루 염색 시 모발 색상 81
9. 탈색모의 고명도 블루 염색 시 모발 색상 86
10. 건강모의 저명도 블루 염색 시 모발 색상 91
11. 건강모의 중명도 블루 염색 시 모발 색상 96
12. 건강모의 고명도 블루 염색 시 모발 색상 101
13. 탈색모의 저명도 옐로우 염색 시 모발 색상 106
14. 탈색모의 중명도 옐로우 염색 시 모발 색상 111
15. 탈색모의 고명도 옐로우 염색 시 모발 색상 116
16. 건강모의 저명도 옐로우 염색 시 모발 색상 121
17. 건강모의 중명도 옐로우 염색 시 모발 색상 126
18. 건강모의 고명도 옐로우 염색 시 모발 색상 131
제2절 피그멘테이션 처리 방법에 따른 손상도 특성 136
1. SEM(scanning electron microscope) 136
2. 인장강도 150
3. 메틸렌블루(Methylene blue) 측정 154
제5장 결론 158
참고문헌 161
국문초록 165
〈Table 3-1〉 NBS(National Bureau of Standards)의 색차 기준 6단계 43
〈Table 4-1〉 Results of spectrophotometer measurements when bleach hair Low-brightness red dye 47
〈Table 4-2〉 Results of spectrophotometer measurements when bleach hair medium-brightness red dye 52
〈Table 4-3〉 Results of spectrophotometer measurements when bleach hair high-brightness red dye 57
〈Table 4-4〉 Results of spectrophotometer measurements when virgin hair low-brightness red dye 62
〈Table 4-6〉 Results of spectrophotometer measurements when virgin hair medium-brightness red dye 67
〈Table 4-6〉 Results of spectrophotometer measurements when virgin hair high-brightness red dye 72
〈Table 4-7〉 Results of spectrophotometer measurements when bleach hair low-brightness blue dye 77
〈Table 4-8〉 Results of spectrophotometer measurements when bleach hair medium-brightness blue dye 82
〈Table 4-9〉 Results of spectrophotometer measurements when bleach hair high-brightness blue dye 87
〈Table 4-10〉 Results of spectrophotometer measurements when virgin hair low-brightness blue dye 92
〈Table 4-11〉 Results of spectrophotometer measurements when virgin hair medium-brightness blue dye 97
〈Table 4-12〉 Results of spectrophotometer measurements when virgin hair high-brightness blue dye 102
〈Table 4-13〉 Results of spectrophotometer measurements when bleach hair low-brightness yellow dye 107
〈Table 4-14〉 Results of spectrophotometer measurements when bleach hair medium-brightness yellow dye 112
〈Table 4-15〉 Results of spectrophotometer measurements when bleach hair high-brightness yellow dye 117
〈Table 4-16〉 Results of spectrophotometer measurements when virgin hair low-brightness yellow dye 122
〈Table 4-17〉 Results of spectrophotometer measurements when virgin hair medium-brightness yellow dye 127
〈Table 4-18〉 Results of spectrophotometer measurements when virgin hair high-brightness yellow dye 132
〈Table 4-19〉 저명도염색에서 피그멘테이션 방법 차이에 따른 인장강도 변화 151
〈Table 4-20〉 중명도염색에서 피그멘테이션 방법 차이에 따른 인장강도 변화 152
〈Table 4-21〉 고명도염색에서 피그멘테이션 방법 차이에 따른 인장강도 변화 153
〈Table 4-22〉 Statistical significance according to methylene blue staining method in low level dying 155
〈Table 4-23〉 Statistical significance according to methylene blue staining method in medium level dying 156
〈Table 4-24〉 Statistical significance according to methylene blue staining method in high level dying 157
〈Fig. 2-1〉 The chemical structure of hair dye couplers 32
〈Fig. 2-2〉 Formation of simple hair dyes from PPD with hair couplers 34
〈Fig. 3-1〉 연구모형 37
〈Fig. 4-1〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with low-brightness red dye) 48
〈Fig. 4-2〉 Difference in the method of dyeing in the low-brightness red dye (BH-S0) 49
〈Fig. 4-3〉 Difference in the method of dyeing in the low-brightness red dye (BH-S10) 49
〈Fig. 4-4〉 Difference in the method of dyeing in the low-brightness red dye (BH-S20) 50
〈Fig. 4-5〉 Difference in the method of dyeing in the low-brightness red dye (BH-S30) 50
〈Fig. 4-6〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with medium-brightness red dye) 53
〈Fig. 4-7〉 Difference in the method of dyeing in the medium-brightness red dye (BH-S0) 54
〈Fig. 4-8〉 Difference in the method of dyeing in the medium-brightness red dye (BH-S10) 54
〈Fig. 4-9〉 Difference in the method of dyeing in the medium-brightness red dye (BH-S20) 55
〈Fig. 4-10〉 Difference in the method of dyeing in medium-brightness red dye (BH-S30) 55
〈Fig. 4-11〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with high-brightness red dye) 58
〈Fig. 4-12〉 Difference in the method of dyeing in the high-brightness red dye (BH-S0) 59
〈Fig. 4-13〉 Difference in the method of dyeing in the high-brightness red dye (BH-S10) 59
〈Fig. 4-14〉 Difference in the method of dyeing in the high-brightness red dye (BH-S20) 60
〈Fig. 4-15〉 Difference in the method of dyeing in the high-brightness red dye (BH-S30) 60
〈Fig. 4-16〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with low-brightness red dye) 63
〈Fig. 4-17〉 Difference in the method of dyeing in the low-brightness red dye (VH-S0) 64
〈Fig. 4-18〉 Difference in the method of dyeing in the low-brightness red dye (VH-S0) 64
〈Fig. 4-19〉 Difference in the method of dyeing in the low-brightness red dye (VH-S20) 65
〈Fig. 4-20〉 Difference in the method of dyeing in the low-brightness red dye (VH-S30) 65
〈Fig. 4-21〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with medium-brightness red dye) 68
〈Fig. 4-22〉 Difference in the method of dyeing in medium-brightness red dye (VH-S0) 69
〈Fig. 4-23〉 Difference in the method of dyeing in medium-brightness red dye (VH-S10) 69
〈Fig. 4-24〉 Difference in the method of dyeing in medium-brightness red dye (VH-S20) 70
〈Fig. 4-25〉 Difference in the method of dyeing in medium-brightness red dye (VH-S30) 70
〈Fig. 4-26〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with high-brightness red dye) 73
〈Fig. 4-27〉 Difference in the method of dyeing in the high-brightness red dye (VH-S0) 74
〈Fig. 4-28〉 Difference in the method of dyeing in the high-brightness red dye (VH-S10) 74
〈Fig. 4-29〉 Difference in the method of dyeing in the high-brightness red dye (VH-S20) 75
〈Fig. 4-30〉 Difference in the method of dyeing in the high-brightness red dye (VH-S30) 75
〈Fig. 4-31〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with low-brightness blue dye) 78
〈Fig. 4-32〉 Difference in the method of dyeing in the low-brightness blue dye (BH-S0) 79
〈Fig. 4-33〉 Difference in the method of dyeing in the low-brightness blue dye (BH-S10) 79
〈Fig. 4-34〉 Difference in the method of dyeing in the low-brightness blue dye (BH-S20) 80
〈Fig. 4-35〉 Difference in the method of dyeing in the low-brightness blue dye (BH-S30) 80
〈Fig. 4-36〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with medium-brightness blue dye) 83
〈Fig. 4-37〉 Difference in the method of dyeing in medium-brightness blue dye (BH-S0) 84
〈Fig. 4-38〉 Difference in the method of dyeing in medium-brightness blue dye (BH-S10) 84
〈Fig. 4-39〉 Difference in the method of dyeing in medium-brightness blue dye (BH-S20) 85
〈Fig. 4-40〉 Difference in the method of dyeing in medium-brightness blue dye (BH-S30) 85
〈Fig. 4-41〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with high-brightness blue dye) 88
〈Fig. 4-42〉 Difference in the method of dyeing in the high-brightness blue dye (BH-S0) 89
〈Fig. 4-43〉 Difference in the method of dyeing in the high-brightness blue dye (BH-S10) 89
〈Fig. 4-44〉 Difference in the method of dyeing in the high-brightness blue dye (BH-S20) 90
〈Fig. 4-45〉 Difference in the method of dyeing in the high-brightness blue dye (BH-S30) 90
〈Fig. 4-46〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with low-brightness blue dye) 93
〈Fig. 4-47〉 Difference in the method of dyeing in the low-brightness blue dye (VH-S0) 94
〈Fig. 4-48〉 Difference in the method of dyeing in the low-brightness blue dye (VH-S10) 94
〈Fig. 4-49〉 Difference in the method of dyeing in the low-brightness blue dye (VH-S20) 95
〈Fig. 4-50〉 Difference in the method of dyeing in the low-brightness blue dye (VH-S30) 95
〈Fig. 4-51〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with medium-brightness blue dye) 98
〈Fig. 4-52〉 Difference in the method of dyeing in medium-brightness blue dye (VH-S0) 99
〈Fig. 4-53〉 Difference in the method of dyeing in medium-brightness blue dye (VH-S10) 99
〈Fig. 4-54〉 Difference in the method of dyeing in medium-brightness blue dye (VH-S20) 100
〈Fig. 4-55〉 Difference in the method of dyeing in medium-brightness blue dye (VH-S30) 100
〈Fig. 4-56〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with high-brightness blue dye) 103
〈Fig. 4-57〉 Difference in the method of dyeing in the high-brightness blue dye (VH-S0) 104
〈Fig. 4-58〉 Difference in the method of dyeing in the high-brightness blue dye (VH-S10) 104
〈Fig. 4-59〉 Difference in the method of dyeing in the high-brightness blue dye (VH-S20) 105
〈Fig. 4-60〉 Difference in the method of dyeing in the high-brightness blue dye (VH-S30) 105
〈Fig. 4-61〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with low-brightness yellow dye) 108
〈Fig. 4-62〉 Difference in the method of dyeing in the low-brightness yellow dye (BH-S0) 109
〈Fig. 4-63〉 Difference in the method of dyeing in the low-brightness yellow dye (BH-S10) 109
〈Fig. 4-64〉 Difference in the method of dyeing in the low-brightness yellow dye (BH-S20) 110
〈Fig. 4-65〉 Difference in the method of dyeing in the low-brightness yellow dye (BH-S30) 110
〈Fig. 4-66〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with medium-brightness yellow dye) 113
〈Fig. 4-67〉 Difference in the method of dyeing in medium-brightness yellow dye (BH-S0) 114
〈Fig. 4-68〉 Difference in the method of dyeing in medium-brightness yellow dye (BH-S10) 114
〈Fig. 4-69〉 Difference in the method of dyeing in medium-brightness yellow dye (BH-S20) 115
〈Fig. 4-70〉 Difference in the method of dyeing in medium-brightness yellow dye (BH-S30) 115
〈Fig. 4-71〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Bleach hair with high-brightness yellow dye) 118
〈Fig. 4-72〉 Difference in the method of dyeing in the high-brightness yellow dye (BH-S0) 119
〈Fig. 4-73〉 Difference in the method of dyeing in the high-brightness yellow dye (BH-S10) 119
〈Fig. 4-74〉 Difference in the method of dyeing in the high-brightness yellow dye (BH-S20) 120
〈Fig. 4-75〉 Difference in the method of dyeing in the high-brightness yellow dye (BH-S30) 120
〈Fig. 4-76〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with low-brightness yellow dye) 123
〈Fig. 4-77〉 Difference in the method of dyeing in the low-brightness yellow dye (VH-S0) 124
〈Fig. 4-78〉 Difference in the method of dyeing in the low-brightness yellow dye (VH-S10) 124
〈Fig. 4-79〉 Difference in the method of dyeing in the low-brightness yellow dye (VH-S20) 125
〈Fig. 4-80〉 Difference in the method of dyeing in the low-brightness yellow dye (VH-S30) 125
〈Fig. 4-81〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with medium-brightness yellow dye) 128
〈Fig. 4-82〉 Difference in the method of dyeing in medium-brightness yellow dye (VH-S0) 129
〈Fig. 4-83〉 Difference in the method of dyeing in medium-brightness yellow dye (VH-S10) 129
〈Fig. 4-84〉 Difference in the method of dyeing in medium-brightness yellow dye (VH-S20) 130
〈Fig. 4-85〉 Difference in the method of dyeing in medium-brightness yellow dye (VH-S30) 130
〈Fig. 4-86〉 Variation of color distance(△E) by pigmentation dyeing method and washing times (Virgin hair with high-brightness yellow dye) 133
〈Fig. 4-87〉 Difference in the method of dyeing in the high-brightness yellow dye (VH-S0) 134
〈Fig. 4-88〉 Difference in the method of dyeing in the high-brightness yellow dye (VH-S10) 134
〈Fig. 4-89〉 Difference in the method of dyeing in the high-brightness yellow dye (VH-S20) 135
〈Fig. 4-90〉 Difference in the method of dyeing in the high-brightness yellow dye (VH-S30) 135
〈Fig. 4-91〉 저명도 건강모 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 138
〈Fig. 4-92〉 중명도 건강모 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 139
〈Fig. 4-93〉 고명도 건강모 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 140
〈Fig. 4-94〉 저명도 손상모 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 141
〈Fig. 4-95〉 중명도 손상모 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 142
〈Fig. 4-96〉 고명도 손상모 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 143
〈Fig. 4-97〉 저명도 손상모 샴푸처리 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 144
〈Fig. 4-98〉 중명도 손상모 샴푸처리 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 145
〈Fig. 4-99〉 고명도 손상모 샴푸처리 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 146
〈Fig. 4-100〉 저명도 건강모 샴푸처리 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 147
〈Fig. 4-101〉 중명도 건강모 샴푸처리 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 148
〈Fig. 4-102〉 고명도 건강모 샴푸처리 그룹 염색에서 pigmentation 방법에 따른 FE-SEM 149
〈Fig. 4-103〉 저명도염색에서 피그멘테이션 방법 차이에 따른 인장강도 변화 151
〈Fig. 4-104〉 중명도염색에서 피그멘테이션 방법 차이에 따른 인장강도 변화 152
〈Fig. 4-105〉 고명도염색에서 피그멘테이션 방법 차이에 따른 인장강도 변화 153
〈Fig. 4-106〉 Statistical significance according to methylene blue staining method in low level dying 155
〈Fig. 4-107〉 Statistical significance according to methylene blue staining method in medium level dying 156
〈Fig. 4-108〉 Statistical significance according to methylene blue staining method in high level dying 157