표제지
요 약
Abstract
목차
감사의 글 11
Ⅰ. 서론 12
1. 대체제독제 선정 및 제독반응기작 16
1.1. 대체제독제의 선정 기준 16
1.2. 제독반응기작(decontamination reaction mechanism) 17
1.2.1. 가수분해(hydrolysis) 17
1.2.1.1 GB 작용제 17
1.2.1.2 VX 작용제 18
1.2.1.3 HD 작용제 19
1.2.2. Hypochlorite ion을 이용한 화학작용제 가수분해 19
1.2.2.1 GB 작용제 19
1.2.2.2 VX 작용제 20
1.2.2.3 HD 작용제 20
Ⅱ. 실험 22
1. 실험재료 22
1.1. 제독제 : Hydorxide계, Hypochlorite계 22
1.2. 작용제 23
2. 실험기기 및 조건 23
2.1. 가스크로마토그래피(GC) 23
2.2. Water bath 23
2.3. Voltax 23
3. 제독반응 실험절차 24
Ⅲ. 결과 및 고찰 25
1. Hydroxide계 제독제 25
1.1. 대상 제독제 : NaOH, Na2CO3, NHOH 25
1.2. 제독몰비에 따른 제독효과 25
1.2.1. GB작용제에 대한 제독효과 25
1.2.2. VX작용제에 대한 제독효과 26
1.3. 제독시간에 따른 제독효과 28
1.4. 평가 29
2. Hypochlorite계 제독제 30
2.1. 대상 제독제 : Sodium hypochlorite, Calsium hypochlorite 30
2.2. 제독몰비에 대한 제독 효과 30
2.2.1. GB작용제에 대한 제독효과 30
2.2.2. VX작용제에 대한 제독효과 31
2.2.3. HD작용제에 대한 제독효과 32
2.3. 제독시간에 따른 제독 효과 34
2.4. 작용제별 제독효과 비교 35
2.5. 환경 유해성 평가 35
2.5.1. 물과 반응시 생성물 35
2.5.2. 시간변화에 따른 유효염소의 변화 36
2.5.3. 생태계에 미치는 영향 36
2.6. 평가 36
Ⅳ. 결론 38
참고문헌 40
Table 1. Species and characteristics of decontamination agents 16
Table 2. Use of decontamination agents 22
Table 3. GC condition for analysis 23
Table 4. Decontamination effects of GB by decontamination agents of hydroxide group 25
Table 5. Decontamination effects of VX by decontamination agents of hydroxide group 27
Table 6. Decontamination effects with time duration of decontaminant having hydroxide group 28
Table 7. Decontamination effects of GB by decontamination agents having hypochlorite group 30
Table 8. Decontamination effects of VX by decontamination agents having hypochlorite group 32
Table 9. Decontamination effects of HD by decontamination agents having hypochlorite group 33
Table 10. Decontamination effects with time duration of decontaminant having hypochlorite group 34
Table 11. Decontamination effects of different hypochlorite group decontaminants 35
Table 12. Duration of effective chloride quantity with time 36
Table 13. Effects on ecosystem 36
Figure 1. Hydrolysis of VX 18
Figure 2. Hydrolysis of GB in hypochlorite ion 19
Figure 3. Hypochlorite ion Reaction of VX 20
Figure 4. Oxidation and removing reaction of HD 20
Figure 5. Oxidation and removing reaction of HD(Continued) 21
Figure 6. Decontamination effects of GB by decontamination agents of hydroxide group 21
Figure 7. Decontamination effects of VX by decontamination agents of hydroxide group 27
Figure 8. Decontamination effects with time duration of decontaminant having hydroxide group 29
Figure 9. Decontamination effects of GB by decontamination agents having hypochlorite group 31
Figure 10. Decontamination effects of VX by decontamination agents having hypochlorite group 32
Figure 11. Decontamination effects of HD by decontamination agents having hypochlorite group 33
Figure 12. Decontamination effects with time duration of decontaminant having hypochlorite group 34